• Title of article

    Isolation and characterization of a monomeric, solvent coordinated ruthenium(II)carbene cation relevant to olefin metathesis

  • Author/Authors

    Peter Hofmann، نويسنده , , Martin A.O Volland، نويسنده , , Michael Hansen، نويسنده , , Frank Eisentr?ger، نويسنده , , Jürgen H Gross، نويسنده , , Katharina Stengel، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    88
  • To page
    92
  • Abstract
    The isolation as well as spectroscopic and structural characterization of [(κ2-tBu2PCH2PtBu2)ClRuCHCHC(CH3)2(CH3CN)]+ ([5+]), a solvent-coordinated monomeric ruthenium(II)carbene cation with a rigid cis-stereochemistry of two phosphines, are reported. Its relevance for the mechanism of olefin metathesis catalyzed by such complexes is discussed and distinct differences compared to complexes with the usual trans-phosphine stereochemistry are noted.
  • Keywords
    carbene complexes , homogenous catalysis , Density functional theory calculations , Ruthenium , Metathesis
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370897

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1370897