Title of article :
Trends in back-bonding in the series trans-[M(CCR)Cl(PH3)4] (M=Fe, Ru, Os; R=H, Ph, C6H4NO2-4)
Author/Authors :
Christopher D. Delfs، نويسنده , , Rob Stranger، نويسنده , , Mark G. Humphrey، نويسنده , ,
Andrew M. McDonagh، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Pages :
5
From page :
208
To page :
212
Abstract :
The electronic structure of the complexes trans-[M(CCR)Cl(PH3)4] (M=Fe, Ru, Os; R=H, Ph, C6H4NO2-4) has been investigated using approximate density functional theory in order to examine the MC back-bonding interaction. For all three metal systems, the π back-bonding increases in the order R=H
Keywords :
Metal–carbon backbonding , Density functional theory , Relativistic effects
Journal title :
Journal of Organometallic Chemistry
Serial Year :
2000
Journal title :
Journal of Organometallic Chemistry
Record number :
1370942
Link To Document :
