Title of article
TaCl5-catalyzed reaction of 1-alkenes with n-alkyl Grignard reagents
Author/Authors
Rifkat M. Sultanov، نويسنده , , Ruslan R. Ismagilov، نويسنده , , Natalʹya R. Popodʹko، نويسنده , , Artur R. Tulyabaev، نويسنده , , Usein M. Dzhemilev، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2013
Pages
6
From page
51
To page
56
Abstract
Tantalum-catalyzed reaction of organomagnesium compounds (OMCs), bearing normal alkyl radicals, with 1-alkenes to afford novel iso-alkylmagnesiums has been systematically studied for the first time. The probable mechanism of the reaction implying the intermediate formation of β,β′-dialkyl substituted tantalacyclopentanes is discussed.
Keywords
Organomagnesiums , Catalysis , Tantalum complexes , 1-Alkenes
Journal title
Journal of Organometallic Chemistry
Serial Year
2013
Journal title
Journal of Organometallic Chemistry
Record number
1371251
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