Title of article
Rhodium and palladium complexes from 1,1′ and 1,2 ferrocenylphosphine as bidentate ligands. Versatile coordination
Author/Authors
Roland Broussier، نويسنده , , Emmanuelle Bentabet، نويسنده , , Myriam Laly، نويسنده , , Philippe Richard، نويسنده , , Lyudmila G Kuzʹmina، نويسنده , , Philippe Serp، نويسنده , , Nigel Wheatley، نويسنده , , Philippe Kalck، نويسنده , , Bernard Gautheron، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
9
From page
77
To page
85
Abstract
The complexation of the mixed bidentate ligands 1-diphenylphosphino-1′-diphenylthiophosphinoferrocenyl and 1,2-bis(diphenylphosphino)ferrocenyl with rhodium(I) and palladium(II) species yield a range of mono- and dirhodium or palladium complexes. Their interest as possible catalysts for alkene hydroformylation and alkoxycarbonylation and Heck coupling reactions has been assessed. Fe[C5Me4P(S)Ph2][C5Me4PPh2]PdCl2 and Fe[C5H2-1,2-(PPh2)2-4-tBu][C5H5]PdCl2 have been characterized by single-crystal X-ray diffraction studies.
Keywords
Ferrocene , Phosphine , Rhodium , Palladium , Catalysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1371390
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