Title of article
Reactions of cyclometalated carbonyliron complex derived from thienyl Schiff base
Author/Authors
Wen-Shu Hwang، نويسنده , , Dongliang Wang&Alan D. Hutson، نويسنده , , Michael Y Chiang، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
5
From page
231
To page
235
Abstract
Cyclometalated hexacarbonyldiiron complex 2, which derived from N-(2-thienylmethylidene)aniline, undergoes (1) thermolysis to recover the original Schiff base 1, (2) reduction to form a hydrogenation product of the original thienyl Schiff base 3, (3) substitution to form a phosphine-substituted complex 4, and (4) chemical as well as electrochemical oxidation to produce a γ-lactam 5.
Keywords
N-(2-thienylmethylidene)aniline , Cyclometalated hexacarbonyldiiron complex , ?-lactam , Carbonylation
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1371419
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