Title of article :
Bond rotamers and calculated 11B-NMR chemical shifts in boron-containing cluster chemistry. Some effects in the {nido-7,8,10-PC2B8} system
Author/Authors :
Daniel L Ormsby، نويسنده , , Robert Greatrex، نويسنده , , Bohumil ?t??br، نويسنده , , John D Kennedy، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Abstract :
Rotamer changes about the exo-cluster C-phenyl bond in 7-Ph-nido-7,8,10-PC2B8H10 have significant differential effects of up to ca. 6 ppm on the nuclear shieldings of adjacent boron atoms within the cluster. The phenomenon has some more general implications.
Keywords :
Boranes , DFT/GIAO structural/NMR calculations , rotamers , 11B nuclear shielding , Monoheterodicarbaborane clusters
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
