Title of article
Bond rotamers and calculated 11B-NMR chemical shifts in boron-containing cluster chemistry. Some effects in the {nido-7,8,10-PC2B8} system
Author/Authors
Daniel L Ormsby، نويسنده , , Robert Greatrex، نويسنده , , Bohumil ?t??br، نويسنده , , John D Kennedy، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
5
From page
61
To page
65
Abstract
Rotamer changes about the exo-cluster C-phenyl bond in 7-Ph-nido-7,8,10-PC2B8H10 have significant differential effects of up to ca. 6 ppm on the nuclear shieldings of adjacent boron atoms within the cluster. The phenomenon has some more general implications.
Keywords
Boranes , DFT/GIAO structural/NMR calculations , rotamers , 11B nuclear shielding , Monoheterodicarbaborane clusters
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1371454
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