• Title of article

    Terminal chloroaminophosphido and aminophosphinidene complexes of molybdenum

  • Author/Authors

    Brian T. Sterenberg، نويسنده , , Arthur J. Carty، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2001
  • Pages
    6
  • From page
    696
  • To page
    701
  • Abstract
    The phosphido complex [Cp*Mo(CO)3P(Cl)NiPr2] (1, Cp*=C5(CH3)5) was formed by the reaction of Li[Cp*Mo(CO)3] with iPr2NPCl2. Chloride abstraction from 1 leads to the aminophosphinidene complex [Cp*(CO)3MoPNiPr2][AlCl4] (2) which reacts with phenylacetylene to form the metalaphosphacyclobutene complex [Cp*(CO)3H}][AlCl4] (3).
  • Keywords
    Aminophosphinidene , Phosphinidene , Phosphido , Chloroaminophosphido , Molybdenum
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1371681