Title of article
Terminal chloroaminophosphido and aminophosphinidene complexes of molybdenum
Author/Authors
Brian T. Sterenberg، نويسنده , , Arthur J. Carty، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
6
From page
696
To page
701
Abstract
The phosphido complex [Cp*Mo(CO)3P(Cl)NiPr2] (1, Cp*=C5(CH3)5) was formed by the reaction of Li[Cp*Mo(CO)3] with iPr2NPCl2. Chloride abstraction from 1 leads to the aminophosphinidene complex [Cp*(CO)3MoPNiPr2][AlCl4] (2) which reacts with phenylacetylene to form the metalaphosphacyclobutene complex [Cp*(CO)3H}][AlCl4] (3).
Keywords
Aminophosphinidene , Phosphinidene , Phosphido , Chloroaminophosphido , Molybdenum
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1371681
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