Title of article
Vinyl complexes of diruthenium(IV) thiolates
Author/Authors
Rufei Ye، نويسنده , , Ai-Quan Jia، نويسنده , , Qing Ma، نويسنده , , Qun Chen، نويسنده , , Wa-Hung Leung، نويسنده , , Qian-Feng Zhang، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2013
Pages
4
From page
20
To page
23
Abstract
Treatment of [Et4N][RuCl4(MeCN)2] with 2,4,6-trimethylthiophenol (HSMes) in the presence of NaOMe afforded the trigonal–bipyramidal ruthenium(IV) complex [Ru(SMes)4(MeCN)] (1), which reacted with propargylic alcohols HCtriple bond; length of mdashCCR2OH (R = Me, Et) at ambient temperature to give the novel vinyl complexes of diruthenium(IV) thiolates [(μ-SMes)Ru{η1-O,η1-C-OCR2CHdouble bond; length as m-dashC(SMes)}(SMes)]2 (R = Me 2, Et 3). The crystal structures of 2 and 3 have been determined. The Ru−Cα bond distances are 2.011(3) and 2.023(5) Å for 2 and 3, respectively.
Keywords
crystal structure , Vinyl complex , Thiolate , Synthesis , Ruthenium(IV)
Journal title
Journal of Organometallic Chemistry
Serial Year
2013
Journal title
Journal of Organometallic Chemistry
Record number
1371833
Link To Document