Title of article
Synthesis of 2-ynamides by direct palladium-catalyzed oxidative aminocarbonylation of alk-1-ynes
Author/Authors
Bartolo Gabriele، نويسنده , , Giuseppe Salerno، نويسنده , , Lucia Veltri، نويسنده , , Mirco Costa، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
5
From page
84
To page
88
Abstract
A novel synthesis of 2-ynamides (3) by palladium-catalyzed oxidative aminocarbonylation of alk-1-ynes (1) is reported. Reactions are catalyzed by PdI2/KI and are carried out at 100°C in dioxane as the solvent in the presence of dialkylamines (2) as nucleophiles (amine/alk-1-yne molar ratio=1/1) using a 4/1 CO/air mixture (20 atm total pressure at 25°C).
Keywords
Palladium , 2-Ynamides , alk-1-ynes , Amides , Carbonylation , Aminocarbonylation
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1372078
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