Title of article :
Silyl-cupration of a propargylsilane as a test for the reversibility of a metallo-metallation
Author/Authors :
Maria Angeles Cubillo de Dios، نويسنده , , Ian Fleming، نويسنده , , Wibke Friedhoff، نويسنده , , Philip D.W. Woode، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2001
Abstract :
Silyl-cupration of propargylsilanes is normal in giving mainly the product with a silyl group at the terminus and the copper atom in the centre. There is no evidence of the copper atom and the originally-resident silyl group undergoing a retro silyl-cupration to give an allenylsilane.
Keywords :
Metallo-metallation , Silyl-cupration , alkynes , allenylsilane , Propargylsilane
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry