Title of article
Silyl-cupration of a propargylsilane as a test for the reversibility of a metallo-metallation
Author/Authors
Maria Angeles Cubillo de Dios، نويسنده , , Ian Fleming، نويسنده , , Wibke Friedhoff، نويسنده , , Philip D.W. Woode، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
4
From page
69
To page
72
Abstract
Silyl-cupration of propargylsilanes is normal in giving mainly the product with a silyl group at the terminus and the copper atom in the centre. There is no evidence of the copper atom and the originally-resident silyl group undergoing a retro silyl-cupration to give an allenylsilane.
Keywords
Metallo-metallation , Silyl-cupration , alkynes , allenylsilane , Propargylsilane
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1372163
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