Title of article
Regioselective alkylzirconation of internal alkynes
Author/Authors
Shigeo Yamanoi، نويسنده , , Kentaro Seki، نويسنده , , Takashi Matsumoto، نويسنده , , Keisuke Suzuki، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
8
From page
143
To page
150
Abstract
Described herein is the carbometallation of unsymmetrically 1,2-disubstituted alkynes with alkylzirconocene complexes, which are generated by hydrozirconation of alkenes. High regioselectivity is achieved when the two substituents of the alkynes are sterically different enough, giving rise to the regio- and stereodefined trisubstituted alkenes.
Keywords
Regioselective alkylzirconation , Alkylzirconocene complexes , Internal alkynes
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1372175
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