Title of article
Alkylation of nitroarenes with Grignard reagents via oxidative nucleophilic substitution of hydrogen
Author/Authors
Mieczys?aw M?kosza، نويسنده , , Marek Surowiec، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
5
From page
167
To page
171
Abstract
Alkylation of nitroarenes with Grignard reagents via oxidative nucleophilic substitution of hydrogen (ONSH) can be efficiently executed with potasium permanganate in liquid ammonia as an oxidative system for the σH adducts. The addition of RMgX to ArNO2 of stoichiometry 1:1 is accompanied with a redox process apparently of stoichiometry 2:1. Because of that, real stoichiometry of the reaction between nitroarenes and Grignard reagents is ca. 1:1.5.
Keywords
Oxydative nucleophilic substitution of hydrogen , Oxidation , Nitro compounds , Alkylation , Grignard reagents
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1372180
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