Title of article
Hydrosilylation of aldehydes and ketones catalyzed by [Ph3P(CuH)]6
Author/Authors
Bruce H. Lipshutz، نويسنده , , Will Chrisman، نويسنده , , Kevin Noson، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
5
From page
367
To page
371
Abstract
Exposure of an aldehyde or ketone to ≤5 mol% (in copper) of Strykerʹs reagent [Ph3P(CuH)]6 in the presence of one of several silanes affords the corresponding protected alcohol in high yields. Aldehydes can be cleanly reduced in the presence of ketones.
Keywords
copper hydride , Silyl ethers , Hydrosilylation , Selective reductions
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1372209
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