Title of article :
Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4] and its catalytic application to anti-Markovnikov addition of carboxylic acids to terminal alkynes
Author/Authors :
UTTAM KUMAR DAS، نويسنده , , Manish Bhattacharjee and Braja N. Patra ، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2012
Abstract :
The compound, [Ru(dppe)2(CH3CN)Cl][BPh4] (1) has been synthesized from the precursor complex, [(PPh3)2Ru(CH3CN)3Cl][BPh4]. The complex has been structurally characterized. This complex has been found to be an efficient catalyst for the anti-Markovnikov addition of carboxylic acids to alkynes.
Keywords :
Addition of carboxylic acid to alkyne , Catalysis , Ruthenium , alkyne , Carboxylic acid
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
