• Title of article

    Unexpected formation of the novel mixed μ-oxo, μ-sulfido, bis(μ-thiolato) compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]

  • Author/Authors

    Philippe Schollhammer، نويسنده , , François Y Pétillon*، نويسنده , , Jean Talarmin، نويسنده , , Kenneth W. Muir، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    67
  • To page
    70
  • Abstract
    A novel example of CS bond cleavage in a dimolybdenum derivative leads to the formation of the quadruply bridged compound [Mo(IV)2Cp2(μ-O)(μ-S)(μ-SMe)2]. This μ-oxo species is formed by reaction of the chloro-bridged complex [Mo(III)2Cp2(μ-Cl)(μ-SMe)3] with PhCCLi and subsequent hydration at the dimolybdenum site. The MoMo bond length of 2.4900(3) Å in [Mo2Cp2(μ-O)(μ-S)(μ-SMe)2] is unusually short.
  • Keywords
    Dinuclear complexes , Mo?Mo bonding , Oxo and sulfido bridges , Mo(IV) complexes , C?S cleavage
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1372702

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1372702