Title of article :
Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl. Molecular structure of [CpNb(μ-NAr)Me]2 (Ar=2,6-C6H3iPr2)
Author/Authors :
Georgii I. Nikonov، نويسنده , , Philip Mountford، نويسنده , , Lyudmila G. Kuzmina، نويسنده , , Judith A.K. Howard، نويسنده , , Dmitrii A. Lemenovskii، نويسنده , , Dmitry M. Roitershtein، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2001
Abstract :
Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal–metal bonded species [CpNb(μ-NAr)Me]2 (NbNb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield.
Keywords :
X-ray diffraction , ?-Bond metathesis , Metal–metal bond , Niobium , Cyclopentadienyl
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
