• Title of article

    Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl. Molecular structure of [CpNb(μ-NAr)Me]2 (Ar=2,6-C6H3iPr2)

  • Author/Authors

    Georgii I. Nikonov، نويسنده , , Philip Mountford، نويسنده , , Lyudmila G. Kuzmina، نويسنده , , Judith A.K. Howard، نويسنده , , Dmitrii A. Lemenovskii، نويسنده , , Dmitry M. Roitershtein، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2001
  • Pages
    5
  • From page
    25
  • To page
    29
  • Abstract
    Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal–metal bonded species [CpNb(μ-NAr)Me]2 (NbNb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield.
  • Keywords
    X-ray diffraction , ?-Bond metathesis , Metal–metal bond , Niobium , Cyclopentadienyl
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1372771

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1372771