Title of article :
Tungsten carbonyl σ-complexes of nido-carborane thioethers
Author/Authors :
Sergey V. Timofeev، نويسنده , , Maria V. Zakharova، نويسنده , , Elena M. Mosolova، نويسنده , , Ivan A. Godovikov، نويسنده , , Ivan V. Ananyev، نويسنده , , Igor B. Sivaev، نويسنده , , Vladimir I. Bregadze، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2012
Abstract :
Nido-carborane thioethers Cs[X-(CH2)nSMe-7,8-C2B9H11)] (X = 7, 9, n = 0; X = 9, n = 1) were synthesized and their reactions with tungsten carbonyl W(CO)5(THF) were investigated. The corresponding pentacarbonyl tungsten complexes were isolated as cesium salts and characterized. Structure of cesium 7-methylthio-7,8-dicarba-nido-undecaborate was established by single crystal X-ray diffraction.
Keywords :
Tungsten carbonyl complexes , X-ray structure , Synthesis , Nido-carborane thioethers
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
