• Title of article

    Chelation of a proton by oxidized diphosphines

  • Author/Authors

    Adrian-Radu Popescu، نويسنده , , Isabel Rojo، نويسنده , , Francesc Teixidor، نويسنده , , Reijo Sillanp??، نويسنده , , Mikko M. H?nninen، نويسنده , , Clara Vi?as، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2012
  • Pages
    6
  • From page
    124
  • To page
    129
  • Abstract
    The chelation of a proton by oxidized diphosphines is studied for the first time both experimentally and theoretically. As a proof of concept the rare case where two different H-bond systems exist in one compound, H[7,8-(OPiPr2)2-7,8-nido-C2B9H10] is reported. Based on NBO, QTAIM and ELF calculations, the P–O⋯H+⋯O–P interactions were characterized as strong hydrogen bonds.
  • Keywords
    Hydrogen bond , phosphines , Carboranes , DFT calculations , Oxidation
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2012
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1372827

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1372827