Title of article :
Synthesis, structure and redox properties of new cobalt(II) and nickel(II) complexes with 6-ferrocenyl-2,2′-bipyridyl
Author/Authors :
Anna Goldberg، نويسنده , , Mikhail Kiskin، نويسنده , , Vitali Grinberg، نويسنده , , Sergey Kozyukhin، نويسنده , , Artem Bogomyakov، نويسنده , , Irina Utepova، نويسنده , , Aleksey Sidorov، نويسنده , , Oleg Chupakhin، نويسنده , , Igor Eremenko، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Abstract :
New ionic complexes [ML2(MeCN)2]∙2Otf (M = Co or Ni; L = 6-ferrocenyl-2,2′-bipyridyl) were synthesized and characterized by single-crystal X-ray diffraction. Cyclic voltammograms of the compounds [ML2(MeCN)2]∙2Otf in CH2Cl2 show good cycle stability over 100 cycles in the quasi-reversible oxidation potential range (from −0.25 to 0.5 V).
Keywords :
Ferrocenyl ligand , X-ray analysis , Electrochemistry , Heterometallic complexes , Electronic spectra
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
