Title of article :
CuI-catalyzed tandem carbomagnesiation/carbonyl addition of Grignard reagents with acetylenic ketones: Convenient access to tetrasubstituted allylic alcohols
Author/Authors :
Meihua Xie، نويسنده , , Chengyou Feng، نويسنده , , Jitan Zhang، نويسنده , , Changqing Liu، نويسنده , , Kuang Fang، نويسنده , , Guanying Shu، نويسنده , , Wansheng Zuo، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Abstract :
Highly functionalized tetrasubstituted allylic alcohols were prepared conveniently by CuI-catalyzed tandem carbomagnesiation/carbonyl addition of Grignard reagents with acetylenic ketones. The obtained allylic alcohols can be further transformed to polysubstituted indenes by intramolecular cyclization.
Keywords :
allylic alcohol , Acetylenic ketone , CuI , Grignard reagent , Indene
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
