Title of article
CuI-catalyzed tandem carbomagnesiation/carbonyl addition of Grignard reagents with acetylenic ketones: Convenient access to tetrasubstituted allylic alcohols
Author/Authors
Meihua Xie، نويسنده , , Chengyou Feng، نويسنده , , Jitan Zhang، نويسنده , , Changqing Liu، نويسنده , , Kuang Fang، نويسنده , , Guanying Shu، نويسنده , , Wansheng Zuo، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
5
From page
3397
To page
3401
Abstract
Highly functionalized tetrasubstituted allylic alcohols were prepared conveniently by CuI-catalyzed tandem carbomagnesiation/carbonyl addition of Grignard reagents with acetylenic ketones. The obtained allylic alcohols can be further transformed to polysubstituted indenes by intramolecular cyclization.
Keywords
allylic alcohol , Acetylenic ketone , CuI , Grignard reagent , Indene
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373237
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