• Title of article

    Spin chemistry of organometallic compounds: Part 1. Interaction of N-bromohexamethyldisilazane with allyltriethylstannane

  • Author/Authors

    Marc B. Taraban، نويسنده , , Alexander I. Kruppa، نويسنده , , Vladimir I. Rakhlin، نويسنده , , Stanislav I. Grigorʹev، نويسنده , , Olga S. Volkova، نويسنده , , Rudolph G. Mirskov، نويسنده , , Tatyana V. Leshina، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2001
  • Pages
    5
  • From page
    12
  • To page
    16
  • Abstract
    It has been shown, on the basis of the analysis of CIDNP effects, that allene and (Me3Si)2NH — major products of the photoinduced reaction of Et3SnCH2CHCH2 and (Me3Si)2NBr — result from a radical pair comprised of radical dotCH2CHBrCH2SnEt3 and radical dotN(SiMe3)2 free radicals. Allene is formed through the β-cleavage of the short-lived homolytic substitution product Et3SnCH2CBrCH2.
  • Keywords
    Free radicals , ?-Cleavage , Homolytic substitution , CIDNP , Radical pairs
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1373278

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1373278