Title of article
Oxidative esterification of alkenes via π- and σ-organopalladium complexes: new pathways for the reaction
Author/Authors
N.Yu. Kozitsyna، نويسنده , , A.A. Bukharkina، نويسنده , , M.V. Martens، نويسنده , , M.N. Vargaftik، نويسنده , , I.I. Moiseev، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
7
From page
69
To page
75
Abstract
New mechanistic data on the oxidative esterification of alkenes were obtained in the study of the reaction of Pd(II) acetate with hex-1-ene, methylcyclohex-1-ene and racemic α-pinene in a chloroform solution. High yields of unsaturated esters with terminal alcohol group were found in the oxidation of hex-1-ene, while the exocyclic methyl groups in methylcyclohex-1-ene and α-pinene remain untouched.
Keywords
Palladium , ?-complex , Methylcyclohex-1-ene , carbocations , ?-Pinene , Regioselectivity , ?-complex , Hex-1-ene , Reaction mechanism , Oxidative esterification
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1373286
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