Title of article
Cationic palladacycles as catalyst precursors for phenyl acetylene polymerization
Author/Authors
N. Mungwe، نويسنده , , A.J. Swarts، نويسنده , , S.F. Mapolie، نويسنده , , G. Westman، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
9
From page
3527
To page
3535
Abstract
Novel cationic palladacycles based on benzylidene-2,6-diisopropylphenylimines were prepared via C–H activation using Pd(CH3CN)2Cl2 as metal precursor. The complexes were fully characterized by IR and NMR spectroscopy, mass spectrometry and elemental analysis. The cationic palladacycles were found to be active catalysts for the polymerization of phenylacetylene producing largely trans-cisoidal PPA.
Keywords
Cationic palladacycles , Phenyl acetylene polymerization , Polyphenylacetylene , Benzylidene–amines complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1373296
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