• Title of article

    Stable Pt(IV) vinylic complexes with unusual regioselectivity formed in the reaction of methylpropiolate triple bond activation

  • Author/Authors

    Valentine P Ananikov، نويسنده , , Sergey A. Mitchenko، نويسنده , , Irina P. Beletskaya، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2001
  • Pages
    7
  • From page
    175
  • To page
    181
  • Abstract
    An unusual fact of HCCCOOMe triple bond activation by Pt(IV) iodide leading to the formation of new bis-σ-vinyl complexes [Pt(CHCICOOMe)(CIHCCOOMe)(Sol)3−nIn]2−n (where n=2, 3) with different regioselectivity in vinyl ligands is reported. The isolated complex can be involved in C–C coupling reaction resulting in a head-to-tail connection of vinyl groups in a substituted diene unit.
  • Keywords
    Pt(IV) , C?C bond activation , 2D-NMR , C–C coupling , 195Pt-NMR
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2001
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1373308

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1373308