Title of article
New chiral ferrocenyl-pyridinium salts for non-linear optics
Author/Authors
Karine Roque، نويسنده , , Fabienne Barangé، نويسنده , , Gilbert G.A Balavoine، نويسنده , , Jean-Claude Daran، نويسنده , , Pascal G. Lacroix، نويسنده , , Eric Manoury، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2001
Pages
7
From page
531
To page
537
Abstract
Three enantiomerically pure chiral analogues of 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been synthesized. Their bulk efficiencies in second harmonic generation (SHG) have been measured (from 0 to 0.25 times that of urea). Furthermore, the crystal structures for two of them and for the parent 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been determined by X-ray diffraction studies. Crystal packing could explain the very different SHG bulk efficiencies in this family of materials.
Keywords
Non-linear optics , Pyridinium , Crystal packing , Iron , Ferrocene , Chirality
Journal title
Journal of Organometallic Chemistry
Serial Year
2001
Journal title
Journal of Organometallic Chemistry
Record number
1373441
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