Title of article :
Highly regioselective hydroselenation and double-bond isomerization of terminal alkynes with benzeneselenol catalyzed by bis(triphenylphosphine)palladium(II) dichloride
Author/Authors :
Toshiya Ozaki، نويسنده , , Mao Kotani، نويسنده , , Hiroki Kusano، نويسنده , , Akihiro Nomoto، نويسنده , , Akiya Ogawa، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Abstract :
Bis(triphenylphosphine)palladium(II) dichloride (PdCl2(PPh3)2) catalyzes regioselective addition of benzeneselenol to terminal alkynes and the subsequent double-bond isomerization to afford the corresponding internal alkenyl selenides in good yields.
Keywords :
Selenol , Markovnikov addition , Double-bond isomerization , Palladium , Vinyl selenide
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
