Title of article
Ti–Ru bimetallic complexes: catalysts for ring-closing metathesis
Author/Authors
Pierre Le Gendre، نويسنده , , Michel Picquet، نويسنده , , Philippe Richard، نويسنده , , Claude Moise، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
6
From page
231
To page
236
Abstract
The reaction of the titanocene monophosphanes (1–4) with the dimer [(p-cymene)RuCl2]2 gives the heterobimetallic compounds (p-cymene)[(η5-C5H5)(μ-η5:η1-C5H4(CR2)nPR′2)TiCl2]RuCl2 (5–8). The structure of 8, determined by X-ray diffraction, is reported here. A preliminary assessment of the performance of these complexes in ring-closing metathesis (RCM) revealed an excellent Ti–Ru–allenylidene pre-catalyst 12.
Keywords
Allenylidenes , titanocene , Ruthenium , Heterobimetallic complexes , Metathesis
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1373844
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