Title of article :
The unusual reaction of Ga(C5Me5)3 with a nucleophilic carbene
Author/Authors :
John D. Gorden، نويسنده , , Charles L.B. Macdonald، نويسنده , , Alan H Cowley، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2002
Abstract :
Treatment of Ga(C5Me5)3 with tetramethylimidazol-2-ylidene affords the carbene complex, Ga(C5Me5)2H·carbene (1). The structure of 1 was determined by X-ray crystallography. Possible mechanisms for the formation of 1 are discussed.
Keywords :
Pentamethylcyclopentadienyl , Hydride , Gallium , carbene complex
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
