Title of article :
Intermediates of the PTC carbonylation of benzyl halides by cobalt carbonyls, II
Author/Authors :
Claudia Zucchi، نويسنده , , Giulio Prampolini، نويسنده , , Roland Boese، نويسنده , , Luciano Caglioti، نويسنده , , Howard Alper، نويسنده , , Gyula Palyi، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Abstract :
The structures of intermediates in the PTC carbonylation of two fluorinated benzyl halide substrates were studied. X-ray crystal and molecular structure of 2- and 3-fluorobenzylcobalt tricarbonyl triphenylphosphine derivatives was determined. The supposed influence of structural parameters on the reactivity is discussed.
Keywords :
Carbonylation of fluorinated benzyl halides , PTC-TM (Phase Transfer Catalysis-Transition Metal) , Structure of tricarbonyl triphenylphosphine derivatives , Benzylcobalt carbonyl derivatives
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
