Title of article :
P(MeNMCH2CH2)3N: an effective catalyst for trimethylsilycyanation of aldehydes and ketones
Author/Authors :
Zhigang Wang، نويسنده , , Brandon Fetterly، نويسنده , , John G. Verkade، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2002
Abstract :
The title non-ionic phosphazane base promotes the trimethylsilycyanation of aryl and alkyl aldehydes and ketones in moderate to high yields at room temperature. 29Si-NMR spectral evidence for the intermediacy of a phosphazane phosphorus–silicon adduct is presented.
Keywords :
Transannulation , Bicyclic phosphazane , Aldehyde trimethysilylcyanation , Hypercoordinate silicon , Ketone trimethylsilylcyanation , Aminophosphine catalyst
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
