• Title of article

    Improved dimethylzinc-promoted vinylation of nitrones with vinylboronic esters

  • Author/Authors

    Nageswaran PraveenGanesh، نويسنده , , Cristina de Candia، نويسنده , , Antony Memboeuf، نويسنده , , Gy?rgy Lendvay، نويسنده , , Yves Gimbert، نويسنده , , Pierre Y. Chavant، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2010
  • Pages
    8
  • From page
    2447
  • To page
    2454
  • Abstract
    Vinylboronic esters derived from 4,4,6-trimethyl-[1,3,2]dioxaborinane react with nitrones in the presence of dimethylzinc; nucleophilic addition of the vinyl group onto nitrones produces N-allylic hydroxylamines in fair yields. The sequence is compatible with various functional groups on the vinylic moiety. The mechanism and kinetic aspects are discussed on the basis of DFT calculations.
  • Keywords
    Vinylboronates , Allyl-hydroxylamines , Boron , Transmetallation , zinc
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2010
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1374104

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1374104