Title of article
Interaction of polyhedral boron hydride anions [B10H10]2− and [B12H12]2− with cyclic copper and silver 3,5-bis(trifluoromethyl)pyrazolate complexes
Author/Authors
Victoria N. Tsupreva، نويسنده , , Oleg A. Filippov، نويسنده , , Alexey A. Titov، نويسنده , , Antonina I. Krylova، نويسنده , , Igor B. Sivaev، نويسنده , , Vladimir I. Bregadze، نويسنده , , Lina M. Epstein، نويسنده , , Elena S. Shubina، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
4
From page
1704
To page
1707
Abstract
The interactions of cyclic trinuclear copper {[3,5-(CF3)2Pz]Cu}3 and silver {[3,5-(CF3)2Pz]Ag}3 complexes with polyhedral borate anions [B10H10]2− and [B12H12]2− in solvents of low-polarity were studied using IR spectroscopy (190–290 K). Two types of complexes were found in solution: {[((3,5-CF3)2PzM)3][BnHn]}2− and {[((3,5-CF3)2PzM)3]2[BnHn]}2− (M = Ag, Cu; n = 10, 12). The stability constants of these complexes were determined from IR-spectra.
Keywords
Coinage metal pyrazolate adducts , Decahydro-closo-decaborate , Dodecahydro-closo-dodecaborate , Complex formation , IR spectroscopy
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374285
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