Title of article
The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer
Author/Authors
M. Emin Günay، نويسنده , , Nam?k ?zdemir، نويسنده , , Mahmut Ulusoy، نويسنده , , Melih Uçak، نويسنده , , Muharrem Dinçer، نويسنده , , Bekir Cetinkaya، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
6
From page
2179
To page
2184
Abstract
Deprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium center via NH group to give 5a. The hydrolysis necessitates the study of NHC complex formation in anhydrous media. The new compounds were characterized by spectroscopic methods and three of them (3c, 4c, 5a) by X-ray single-crystal diffraction studies.
Keywords
Imidazolinium salts , Hydrolysis , N-heterocyclic carbenes , Palladacycles , Ring opening
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374460
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