Title of article
Molecular conductors with 8,8′-diiodo cobalt bis(dicarbollide) anion
Author/Authors
Olga N. Kazheva، نويسنده , , Grigorii G. Alexandrov، نويسنده , , Andrey V. Kravchenko، نويسنده , , Vladimir A. Starodub، نويسنده , , Irina A. Lobanova، نويسنده , , Igor B. Sivaev، نويسنده , , Vladimir I. Bregadze، نويسنده , , Lev V. Titov، نويسنده , , Lev I. Buravov، نويسنده , , Oleg A. Dyachenko، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
7
From page
2336
To page
2342
Abstract
New molecular conductors on the base of 8,8′-diiodo cobalt bis(dicarbollide) anion (TTF)[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (1), (BMDT-TTF)4[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (2) and (BEDT-TTF)2[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (3) were synthesized and their crystal structures and electrical conductivities were determined. All the radical cation salts prepared were found to be semiconductors. Some regularities in the crystal structures of the TTF-based radical cation salts with bis(dicarbollide) complexes of transition metals are discussed.
Keywords
8 , 8?-Diiodo-3 , Molecular conductors , 2-dicarbollide) , Tetrathiafulvalenium , Bis(methylenedithio)-tetrathiafulvalenium , crystal structure , Bis(ethylenedithio)-tetrathiafulvalenium , 3?-cobalt bis(1
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374509
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