Title of article :
Terminal pyridine-N ligation at [FeFe] hydrogenase active-site mimic
Author/Authors :
Yue Zhang، نويسنده , , Mingqiang Hu، نويسنده , , Hui-Min Wen، نويسنده , , You-Tao Si، نويسنده , , Chengbing Ma، نويسنده , , Changneng Chen، نويسنده , , Qiutian Liu، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2009
Abstract :
Diiron model complexes (μ-pdt)Fe2(CO)5L with L = pyridine ligands, e.g. py (A), etpy (B), btpy (C), were synthesized as active site analogues of [FeFe] hydrogenase, and characterized by X-ray crystallography and electrochemistry. Pyridine-N ligation was found to be able to tune the redox properties of the diiron centers of model complexes.
Keywords :
Bioinorganic chemistry , Electrochemistry , Organometallic complexes , Pyridine ligand
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
