Title of article
Tert-butylborane: A bis (σ-B–H) ligand in ruthenium hydride chemistry
Author/Authors
Yann Gloaguen، نويسنده , , Gilles Alcaraz، نويسنده , , Laure Vendier، نويسنده , , Sylviane Sabo-Etienne، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
3
From page
2839
To page
2841
Abstract
The reaction of tert-butylborane with the bis(dihydrogen) complex RuH2(η2-H2)2(PCy3)2 leads to the corresponding bis σ-borane complex which is the first example of a monoalkylborane ruthenium bis σ-complex. An alternative route involves the reaction of RuHCl(η2-H2)(PCy3)2 with lithium tert-butylborohydride.
Keywords
Ruthenium , Borane , Sigma-complexes , Dihydrogen
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374619
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