• Title of article

    Spin chemistry of organometallic compounds: 2. Interaction of N-bromohexamethyldisilazane with allyltriorganolsilanes

  • Author/Authors

    Marc B. Taraban، نويسنده , , Alexander I. Kruppa، نويسنده , , Nikolai E. Polyakov، نويسنده , , Mikhail G. Voronkov، نويسنده , , Vladimir I. Rakhlin، نويسنده , , Stanislav V. Grigorʹev، نويسنده , , Olga S. Volkova، نويسنده , , Rudolph G. Mirskov، نويسنده , , Tatyana V. Leshina، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    7
  • From page
    228
  • To page
    234
  • Abstract
    Two instances have been considered demonstrating the influence of organoelement substituent on the reactivity of radicals generated from R3MCH2CHCH2 (M=Si or Sn) in photoinduced interaction with (Me3Si)2NBr. CIDNP studies has allowed to identify two different reaction mechanisms for M=Si or M=Sn which end up in two different sets of reaction products.
  • Keywords
    CIDNP , Homolytic substitution , Free radicals , ?-Cleavage , Radical pairs
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1374810

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1374810