Title of article
Synthesis and structure of novel closo-dodecaborate-based glycerols
Author/Authors
Andrey Semioshkin، نويسنده , , Julia Laskova، نويسنده , , Olga Zhidkova، نويسنده , , Ivan Godovikov، نويسنده , , Zoya Starikova، نويسنده , , Vladimir Bregadze، نويسنده , , Detlef Gabel، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2010
Pages
5
From page
370
To page
374
Abstract
The reactions of oxonium derivatives of [B12H12]2− with different glycerol-based nucleophiles were studied. A series of novel closo-dodecaborate-based glycerols with different net charges on the molecules were prepared. A structure of {2-[2-(4-(2, 3-dihydroxypropyl)-dipiperazinium-1-yl)-ethoxy]-ethoxy}-undecahydro-closo-dodecaborate was determined and the existence of different intermolecular H-bonds was shown.
Keywords
Glycerol , X-ray structure , Closo-dodecaborate , Oxonium derivatives
Journal title
Journal of Organometallic Chemistry
Serial Year
2010
Journal title
Journal of Organometallic Chemistry
Record number
1375110
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