Title of article
Reactions of cyclomanganated complexes with carbon disulfide: routes to η2-aryldithiocarboxylate-Mn(CO)4 complexes and to the trithiocarbonate complex (μ3-CS3)2Mn4(CO)16
Author/Authors
Wade J. Mace، نويسنده , , Lyndsay Main، نويسنده , , Brian K. Nicholson، نويسنده , , Marion Hagyard، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
6
From page
288
To page
293
Abstract
Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn–C bond to give η2-dithiocarboxylato–Mn(CO)4 compounds. With other cyclomanganated substrates such as that from Ph3PS and also with Mn2(CO)10, CS2 gives (μ3-CS3)2Mn4(CO)16 with bridging trithiocarbonate ligands.
Keywords
Cyclomanganates , Carbon disulfide , Insertion , Aryl dithiocarboxylate , manganese , Trithiocarbonate
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1375162
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