• Title of article

    Reactions of cyclomanganated complexes with carbon disulfide: routes to η2-aryldithiocarboxylate-Mn(CO)4 complexes and to the trithiocarbonate complex (μ3-CS3)2Mn4(CO)16

  • Author/Authors

    Wade J. Mace، نويسنده , , Lyndsay Main، نويسنده , , Brian K. Nicholson، نويسنده , , Marion Hagyard، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    6
  • From page
    288
  • To page
    293
  • Abstract
    Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn–C bond to give η2-dithiocarboxylato–Mn(CO)4 compounds. With other cyclomanganated substrates such as that from Ph3PS and also with Mn2(CO)10, CS2 gives (μ3-CS3)2Mn4(CO)16 with bridging trithiocarbonate ligands.
  • Keywords
    Cyclomanganates , Carbon disulfide , Insertion , Aryl dithiocarboxylate , manganese , Trithiocarbonate
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1375162