Title of article
Synthesis of titanium(IV) (cyclopentadienylalkyl)aminate complexes
Author/Authors
Peter B Hitchcock، نويسنده , , G.Jeffery Leigh، نويسنده , , Maria Togrou، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
5
From page
101
To page
105
Abstract
We describe the synthesis of hydrochlorides of [TiCp{(C5H4(CH2)nNMe2}Cl2] (n=2 or 3) via [TiCpCl3] and the lithiated (cyclopentadienylalky)lamine. The –NHMe2 groups in these complexes are not coordinated to the titanium, and probably not in the parent amines either, the metal stereochemistry being the same in each group of compounds. The structure of [TiCp(η5-C5H4CH2CH2CH2NHMe2)Cl2]Cl is described in detail.
Keywords
Titanium , Aminate complexes , Cyclopentadienyl
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1375466
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