Title of article
Cationic iridium–BINAP complex-catalyzed addition of aryl ketones to alkynes and alkenes via directed C–H bond cleavage
Author/Authors
Kyoji Tsuchikama، نويسنده , , Mitsugu Kasagawa، نويسنده , , Yu-Ki Hashimoto، نويسنده , , Kohei Endo، نويسنده , , Takanori Shibata، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
4
From page
3939
To page
3942
Abstract
Cationic Ir complex ([Ir(cod)2]BF4 + BINAP) catalyzed the addition of ortho-C–H bonds in aryl ketones to alkynes, which gave alkenylated products in good to high yield. Styrene derivatives were good substrates, and the enantioselective addition to norbornene was also described.
Keywords
Iridium , C–H bond cleavage , Ketone , alkene , alkyne
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1375502
Link To Document