Title of article :
Unexpected reaction pathway during the palladation of 2,5-diphenylphosphacymantrene
Author/Authors :
?llan G. Ginzburg، نويسنده , , Vasily V. Bashilov، نويسنده , , Fedor M. Dolgushin، نويسنده , , Alexander F. Smol’yakov، نويسنده , , ?lexander S. Peregudov، نويسنده , , Viatchtslav I. Sokolov، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2009
Abstract :
A new reaction of P-alkoxypalladation was found. 2,5-Diphenylphosphacymantrene reacts with Na2PdCl4 and NaOAc in MeOH or EtOH to give P-methoxy or P-ethoxy derivatives with Pd2Cl2 dimeric core. The products 2 and 3 were characterized by 1H, 31P, 13C NMR spectra and X-ray crystal structure data.
Keywords :
Palladation , Phosphacymantrenes , manganese , Palladium
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
