• Title of article

    Synthesis, characterization and olefin polymerization of the nickel catalysts supported by [N,S] ligands

  • Author/Authors

    Yuanbiao Huang، نويسنده , , Wei-Guo Jia، نويسنده , , Guo-Xin Jin، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2009
  • Pages
    5
  • From page
    86
  • To page
    90
  • Abstract
    The novel nickel (II) complexes (2a, 2b) bearing 1-pyridyl-(3-substituedimidazole-2-thione) ligands were synthesized by the reaction of the corresponding ligands with NiBr2(DME). 2a and 2b have been characterized by IR, NMR and elemental analysis. The nickel complexes show high catalytic activities for norbornene polymerization in the presence of MAO (methylaluminoxane), although low activities for ethylene polymerization.
  • Keywords
    Nickel complex , polymerization , Pyridyl-imidazole-2-thione ligands , Norbornene , Ethylene
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2009
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1375536