• Title of article

    Nickel(II) and nickel(0) derivatives of bis(diphenylphosphino)amine: [N(PPh2)2]2Ni, (Ph3P)2Ni[(Ph2P)2NH]. Synthesis, characterization, and some properties

  • Author/Authors

    Vyacheslav V. Sushev، نويسنده , , Alexander N. Kornev، نويسنده , , Yana V. Fedotova، نويسنده , , Yurii A. Kursky، نويسنده , , Tatiana G. Mushtina، نويسنده , , Gleb A. Abakumov، نويسنده , , Lev N. Zakharov، نويسنده , , Arnold L. Rheingold، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2003
  • Pages
    5
  • From page
    89
  • To page
    93
  • Abstract
    Disproportionation of nickel(I) bis(triphenylphosphino)bis(trimethylsilyl)amide, (Ph3P)2NiN(SiMe3)2, in the presence of bis(diphenylphosphino)amine, (Ph2P)2NH, yields Ni(II) and Ni(0) phosphinoamide complexes: [N(Ph2P)2]2Ni (1), (Ph3P)2Ni[(Ph2P)2NH] (2). Ether solution, containing 2 and Ph3P (1:2) reacts with dioxygen (one equivalent) to form triphenylphosphinoxide adduct (Ph3P)2Ni[(Ph2P)2NH⋯OPPh3] (3) in high yield. The crystal structures of compounds 1 and 3 have been determined by X-ray diffraction method.
  • Keywords
    Transition metals , Phosphazanes , X-ray diffraction , nickel , Phosphinoamides
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2003
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1375746

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1375746