Title of article :
Novel stereoselective synthesis of 1,3-dienylsilanes via hydromagnesiation reaction of alkynylsilanes
Author/Authors :
Mingzhong Cai، نويسنده , , Wenyan Hao، نويسنده , , Hong Zhao، نويسنده , , Caisheng Song، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2003
Abstract :
Hydromagnesiation of alkynylsilanes gives (Z)-α-silylvinyl Grignard reagents, which undergo palladium-catalyzed cross-coupling reactions with alkenyl halides to afford stereoselectively 1,3-dienylsilanes in good yields.
Keywords :
cross-coupling reaction , Stereoselective synthesis , Alkynylsilane , Hydromagnesiation , 1 , 3-Dienylsilane
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
