Title of article :
Structure effect of TsDPEN derivatives on enantioselectivity of asymmetric transfer hydrogenation
Author/Authors :
Juntao Liu، نويسنده , , Yinuo Wu، نويسنده , , Xingshu Li، نويسنده , , Albert S.C. Chan، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2008
Abstract :
TsDPEN derivative (3,3′,5,5′-TMTsDPEN) was synthesized and applied in asymmetric transfer hydrogenation of ketones. The influence of chiral ligands’ NCCN dihedral angles to the enantioselectivities of the reaction was discussed.
Keywords :
TMTsDPEN , DFT , Dihedral angel , Enantioselectivity , Asymmetric transfer hydrogenation
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
