Title of article
A sub-stoichiometric tungsten-mediated Pauson–Khand reaction: Scope and limitations
Author/Authors
Patricia Garc?a-Garc?a، نويسنده , , Manuel A. Fern?ndez-Rodr?guez، نويسنده , , Christian Rocaboy، نويسنده , , Facundo Andina، نويسنده , , Enrique Aguilar، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
5
From page
3092
To page
3096
Abstract
Terminal alkynes do not partake in sequential [2+2+1]/benzoannulation reactions with Fischer carbene complexes and highly reactive and sterically hindered olefins; instead, they undergo a Fischer carbene complex-catalyzed Pauson–Khand reaction (PKR). This result has allowed the development, for the first time, of a tungsten-catalyzed PKR, although of limited scope.
Keywords
Fischer carbene , Tungsten carbonyl complexes , Pauson–Khand , Cyclopentenones , alkynes , Chromium carbonyl complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376106
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