Title of article
Chemoselective Diels–Alder reactions of a non-symmetrical bis(carbene)-bridged ditungsten complex with 1,3-dienes
Author/Authors
Karine Ulrich، نويسنده , , Véronique Guerchais، نويسنده , , Karl Heinz D?tz، نويسنده , , Hubert Le Bozec، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
3
From page
260
To page
262
Abstract
The non-symmetrical [(dimethylamino)alkenylcarbene-(methoxy)alkenylcarbene] ditungsten complex 2 undergoes Diels–Alder reactions with 2,3-dimethyl-1,3-butadiene and cyclopentadiene that proceed selectively at the methoxycarbene ligand. Similar Diels–Alder cycloadditions with the symmetrical bis[(methoxy)alkenylcarbene]ditungsten complex 1 are reported for comparison.
Keywords
Diels–Alder reactions , Bridging ligands , carbene complexes , Tungsten
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1376166
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