Title of article
Reactions of nitroxides with metalloporphyrin alkyls bearing beta hydrogens: Aliphatic carbon–carbon bond activation by metal centered radicals
Author/Authors
Kin Shing Chan، نويسنده , , Kin Wah Mak، نويسنده , , Man Kin Tse، نويسنده , , Siu Kwan Yeung، نويسنده , , Bao Zhu Li، نويسنده , , Yun Wai Chan، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
9
From page
399
To page
407
Abstract
Nitroxide-induced beta-hydrogen atom abstraction and beta-elimination of rhodium porphyrin alkyls have been observed. Rhodium(II) porphyrin radical were proposed intermediates to form first and subsequently reacted via aliphatic carbon–carbon bond activation with alkyl substituted nitroxides to yield rhodium porphyrin alkyl complexes.
Keywords
Rhodium porphyrin , Nitroxides , Carbon–carbon bond activation
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376243
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