Title of article
Synthesis and use of mono- or bisxylyl linked bis(benzimidazolium) bromides as carbene precursors for C–C bond formation reactions
Author/Authors
Hayati Türkmen، نويسنده , , Serpil Denizalti، نويسنده , , Ismail Ozdemir، نويسنده , , Engin Cetinkaya، نويسنده , , Bekir Cetinkaya، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
10
From page
425
To page
434
Abstract
Two benzimidazolium moieties linked by one or two xylyls (m- and p-) have been synthesized, characterized and then they were used for Heck coupling reactions as in situ formed catalysts. Mono bridged salts are more efficient as compared to bisbridged salts. In addition, mono bridged salts were converted to Rh–NHC complexes which were tested as catalysts for the arylation of aldehydes.
Keywords
Bridged bisbenzimidazolium salts , Catalytic activities , C–C coupling , Rhodium complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376246
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